Preheat the oven to 350 degrees. Grease two 9" cake tins, and line the bottom with a parchment round, also grease the parchment. Then, lightly flour the cake tins as well.
In a separate bowl, combine the 2 1/3 cups of flour, 1 1/2 tsp of baking powder, 1/2 tsp of baking soda, and 1/2 tsp of salt. Mix and set aside.
In your Kitchenaid mixer fitted with the whisk attachment, add the cup of butter and beat for a minute. Next, add in the 2 cups of sugar, 4 tsp of lemon zest, and two tbsp of lemon juice and whip until they're mixed. After this add in the eggs one at a time, mixing to combine after each egg. You may need to scrape down the sides with a rubber spatula to thoroughly combine.
Once the eggs are combined, alternate adding in the buttermilk and the flour mixture, mixing in between each addition. Scrape down the sides, and mix until all the ingredients come together.
Divide the batter equally between the two pans. Place both of the pans on the middle rack of the oven and bake at 350 degrees for 25-30 minutes, or until they are golden brown and when a toothpick is inserted into the middle it comes back out clean.
Remove from the oven and allow to cool in the pan for 15 minutes. Carefully remove from the pan and allow to cool on a cooling rack for another 45 minutes. Once the cakes are room temperature, wrap them in plastic wrap and place them in the fridge to cool for at least an hour.